Hi,
For POV texture settings, check your File | Settings menu item and go to the "Files" tab. Make sure you've checked "Use object data for POV files" --- and you can also specify your pov header here.
I haven't personally used POV Ray for rendering, so perhaps someone else may have more info, but hope that helps.
I believe there were some interface changes in 5.0.21 that are more recent than the manual screenshots, but the info should *essentially* match up.
Good luck,
Dennis
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